【国外标准】 Standard Test Method for Determination of the Content of Nitroxide Radical (4-Hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl) in Butadiene, Styrene and Isoprene by Cyclic Voltammetry Method

4.1 Nitroxide radicals (H-Tempo, O-Tempo (4-oxo-2,2,6,6-tetramethylpiperidine-1-oxyl), etc.) are widely used as inhibitors of thermopolymerization in the processes of transportation, storage, and separation of monomers (isoprene, butadiene, styrene, etc.). This test method provides a procedure for assaying nitroxide radicals in monomers.4.2 This procedure can be used for determination of the content of nitroxide radicals (H-Tempo, O-Tempo, etc.) in other solvents (dimethyl formamide, DMSO etc.).1.1 This test method is designed to determine the content of nitroxide radical 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (H-Tempo) in butadiene, isoprene, and styrene.1.2 This test method is applicable to samples with nitroxide radical 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (H-Tempo) with concentrations to 100 mg⁄kg. The limit of detection (LOD) is 0.47 mg/kg for nitroxide radical 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (H-Tempo) and the limit of quantitation (LOQ) is 1.6 mg/kg nitroxide radical 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (H-Tempo).1.3 The following applies for the purposes of determining the conformance of the test results using this test method to applicable specifications, results shall be rounded of in accordance with the rounding-off method of Practice E29.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.